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FE Mechanical · knowledge area 11 · 10–15 questions

FE thermodynamics review, tables, laws, cycles

Thermodynamics is 10–15 questions and the area where the property tables decide most answers. Find the state, pick the right table, then apply an energy balance to the right kind of system. Engineering thermodynamics for the whole site is explained here.

Updated Oct 29, 2026 · Not affiliated with NCEES.

What the area covers

The specification lists eleven topics. Grouped:

  • Properties: ideal gases and pure substances, steam and refrigerant tables, quality in the two-phase region.
  • Energy transfers and the laws: work, heat, the first law for closed and open systems, entropy and the second law.
  • Processes and components: isothermal, isentropic, constant-pressure and constant-volume processes; turbines, compressors, pumps, nozzles, valves and heat exchangers.
  • Cycles: power cycles (Rankine, Brayton, Otto, Diesel) and refrigeration and heat pump cycles.
  • Mixtures and air: nonreacting gas mixtures, psychrometrics and HVAC processes.
  • Combustion: fuel and air, theoretical and excess air, products of combustion.

18 thermodynamics problems, every option explained

0 / 18 answered · 0 correct
Question 1 of 18 · Thermodynamics · 10–15 items

Refrigerant-134a enters a condenser at 1.0 MPa as a saturated mixture with a quality of 0.90. It is fully condensed and leaves as saturated liquid at the same pressure. The mass flow rate is 0.050 kg/s. With saturation properties at 1.0 MPa of hf = 107.32 kJ/kg and hg = 270.99 kJ/kg, what is the rate of heat rejection from the condenser?

Given
  • Pressure p = 1.0 MPa
  • Inlet quality x = 0.90
  • Exit state = saturated liquid
  • Mass flow ṁ = 0.050 kg/s
  • hf = 107.32 kJ/kg
  • hg = 270.99 kJ/kg
FindHeat rejection rate (kW)

Solution

h1 = hf + x·hfg = 107.32 + 0.90 × 163.67 = 254.62 kJ/kg, h2 = hf = 107.32 kJ/kg

Q̇ = ṁ(h1 − h2) = 0.050 × 147.30 = 7.37 kW

FE Reference Handbook, Thermodynamics: steady-flow energy equation (heat exchangers).

ṁ·hg uses an absolute enthalpy; heat rejection is the enthalpy difference h1 − hf.
ṁ·h1 is the inlet enthalpy flow, not the change from inlet to exit.
This condenses the full mass flow, as if the inlet were saturated vapor (x = 1).
Only the vapor fraction condenses: Q̇ = ṁ·x·hfg = 0.050 × 0.90 × 163.67 ≈ 7.37 kW.
This uses (1 − x), the liquid already present at the inlet; it is the vapor fraction that releases latent heat.
Question 2 of 18 · Thermodynamics · 10–15 items

In a throttling process, which property remains constant?

Solution

q − w = Δh + ΔKE + ΔPE with q = w = 0 → h2 = h1

The purpose of a throttle is a large pressure drop.
Temperature stays constant only for an ideal gas; a real fluid such as a refrigerant cools sharply when throttled.
Throttling is irreversible, so entropy increases; it is not an isentropic process.
A throttling valve has no work, negligible heat transfer and negligible kinetic energy change, so h1 = h2.
Question 3 of 18 · Thermodynamics · 10–15 items

What is the coefficient of performance (COP) of a refrigerator operating between −5 °C and 25 °C, assuming it operates on an ideal reversed Carnot cycle?

Given
  • Cold reservoir TL = −5 °C
  • Hot reservoir TH = 25 °C
FindCOP

Solution

COPR = TL/(TH − TL) = 268.15 K/(298.15 − 268.15) K = 8.94

FE Reference Handbook, Thermodynamics: Carnot cycle (refrigeration).

Plugging Celsius values into TL/(TH − TL) (5/30, sign dropped) gives a meaningless ratio; absolute temperatures are required.
TL/TH = 0.90 is not a COP; a Carnot refrigerator COP divides TL by the temperature difference.
COPR = TL/(TH − TL) = 268.15/30 = 8.94, with temperatures in kelvins.
TH/(TH − TL) is the Carnot heat pump COP, which is the refrigerator COP plus one.
Question 4 of 18 · Thermodynamics · 10–15 items

A Carnot engine operates between a high-temperature reservoir and a low-temperature reservoir. If the engine has an efficiency of 40% when the low-temperature reservoir is maintained at 300 K, determine the percentage increase in the high-temperature reservoir temperature required to achieve an efficiency of 50%.

Given
  • Initial efficiency η1 = 40%
  • Target efficiency η2 = 50%
  • Low reservoir TL = 300 K
FindIncrease in TH (%)

Solution

TH1 = TL/(1 − η1) = 300/0.60 = 500 K, TH2 = 300/0.50 = 600 K

(600 − 500)/500 = 20.0%

FE Reference Handbook, Thermodynamics: Carnot cycle.

600/500 = 1.20 is the ratio of the temperatures, reported as a percentage; the increase is 20.0%.
100/300 compares the change with the cold reservoir temperature instead of the original hot one.
This is the relative increase in efficiency (0.5/0.4), not in the reservoir temperature.
TH = TL/(1 − η): 300/0.6 = 500 K at 40% and 300/0.5 = 600 K at 50%, a 20.0% increase.
Question 5 of 18 · Thermodynamics · 10–15 items
Temp (°C)Sat. Pressure (kPa)Spec. Vol. Liquid, vf (m3/kg)Spec. Vol. Vapor, vg (m3/kg)
150476.160.0010900.39248
160618.230.0011020.30680
170792.180.0011140.24260

Water is held in a closed system at 160 °C with a specific volume of 0.4500 m3/kg. Based on the saturation data provided, which phase region describes the state of the water, and which property table should be used to find its remaining intensive properties?

Solution

v = 0.4500 m3/kg > vg(160 °C) = 0.30680 m3/kg → superheated vapor

A mixture would need vf < v < vg; here v is larger than vg, which would give a quality above 1.
160 °C is far below water's critical temperature of 374 °C.
Steam this close to saturation is not well described by ideal-gas relations; the superheated tables are the accurate source.
Compressed liquid would need v < vf = 0.001102 m3/kg.
At 160 °C, v = 0.4500 m3/kg exceeds vg = 0.30680 m3/kg, so the water is beyond the saturated vapor line.
Question 6 of 18 · Thermodynamics · 10–15 items

Identify the process in the table below that is thermodynamically impossible because it violates the second law of thermodynamics.

ProcessΔSsystem (kJ/K)Heat transfer with surroundingsSurroundings temp (K)
1−2.0Rejects 800 kJ300
2−3.0Rejects 600 kJ300
3+1.0Absorbs 400 kJ400
4+2.5Absorbs 1000 kJ500
Given
  • Process 1: ΔSsys = −2.0 kJ/K, rejects 800 kJ, Tsurr = 300 K
  • Process 2: ΔSsys = −3.0 kJ/K, rejects 600 kJ, Tsurr = 300 K
  • Process 3: ΔSsys = +1.0 kJ/K, absorbs 400 kJ, Tsurr = 400 K
  • Process 4: ΔSsys = +2.5 kJ/K, absorbs 1000 kJ, Tsurr = 500 K
FindProcess that violates the second law

Solution

Sgen = ΔSsys + Qsurr/Tsurr

1: −2.0 + 800/300 = +0.67; 2: −3.0 + 600/300 = −1.0; 3: 1.0 − 400/400 = 0; 4: 2.5 − 1000/500 = +0.5 kJ/K

FE Reference Handbook, Thermodynamics: second law (entropy).

Both have positive or zero total entropy change; heat absorbed from the surroundings lowers Ssurr only by Q/T.
Process 3 gives Sgen = 1.0 − 400/400 = 0, a reversible process, which is allowed.
Process 1 has ΔSsys < 0, but the surroundings gain 800/300 = 2.67 kJ/K, so Sgen = +0.67 kJ/K.
Process 3 gives Sgen = 1.0 − 400/400 = 0, a reversible process; it is allowed, not impossible.
Sgen = ΔSsys + ΔSsurr: process 1 +0.67, process 2 −3.0 + 600/300 = −1.0, process 3 0 (reversible), process 4 +0.5 kJ/K; only process 2 is negative.
Question 7 of 18 · Thermodynamics · 10–15 items

A gas turbine receives air at 1,000 K and 60 m/s and discharges it at 700 K and 150 m/s. The mass flow rate of the air is 4.0 kg/s, and the turbine loses 35 kW of heat to the surroundings. Assuming a constant specific heat Cp = 1.1 kJ/kg·K and neglecting potential energy changes, what is the power output of the turbine?

Given
  • Inlet: T = 1,000 K, V = 60 m/s
  • Outlet: T = 700 K, V = 150 m/s
  • Mass flow = 4.0 kg/s
  • Heat loss = 35 kW
  • Cp = 1.1 kJ/(kg·K)
FindTurbine power output (kW)

Solution

Ẇ = ṁ[cp(T1 − T2) + (V12 − V22)/2] − Q̇loss

Ẇ = 4.0[1.1 × 300 + (602 − 1502)/2000] − 35 = 4.0(330 − 9.45) − 35 = 1,247 kW

FE Reference Handbook, Thermodynamics: steady-flow energy equation.

Ẇ = ṁ[cp(T1 − T2) + (V12 − V22)/2] − Q̇loss = 4.0 × (330 − 9.45) − 35 ≈ 1,247 kW.
This subtracts the heat loss but ignores the kinetic energy gain of the exhaust, which also takes energy from the shaft.
Adding the kinetic energy term reverses its sign; the air leaves faster, so that energy is not available as work.
This reverses the kinetic energy sign and also ignores the 35 kW heat loss.
This adds the heat loss and the kinetic energy term instead of subtracting them; both reduce the shaft output.
Question 8 of 18 · Thermodynamics · 10–15 items

A rigid, adiabatic mixing chamber receives two streams of water (Cp = 4.18 kJ/kg·K). Stream 1 enters at 3.0 kg/s and 360 K, while Stream 2 enters at 2.0 kg/s and 300 K. The streams mix completely and exit as a single stream at uniform temperature. What is the rate of entropy generation for this process?

Given
  • Specific heat Cp = 4.18 kJ/(kg·K)
  • Stream 1: 3.0 kg/s at 360 K
  • Stream 2: 2.0 kg/s at 300 K
FindEntropy generation rate (W/K)

Solution

T3 = (3.0 × 360 + 2.0 × 300)/5.0 = 336 K

Ṡgen = ṁ1cp ln(T3/T1) + ṁ2cp ln(T3/T2) = −0.865 + 0.948 = 0.082 kW/K = 82 W/K

FE Reference Handbook, Thermodynamics: entropy change of incompressible substances.

This is only the entropy increase of the cold stream; the hot stream loses 865 W/K.
This is only the entropy decrease of the hot stream; the cold stream's increase must be added.
Dividing the transferred heat by the inlet temperatures (301/300 − 301/360) ignores that each stream's temperature changes during mixing.
Tmix = 336 K; Sgen = Σṁcpln(T3/Ti) = 12.54 ln(336/360) + 8.36 ln(336/300) = −0.865 + 0.948 = 0.082 kW/K.
Adiabatic does not mean isentropic: mixing streams at different temperatures is irreversible.
Question 9 of 18 · Thermodynamics · 10–15 items

A piston-cylinder device contains 0.2 kg of air at 100 kPa and 300 K. The air is compressed isentropically to 600 kPa. Assuming air is an ideal gas with k = 1.4 and Cv = 0.718 kJ/kg·K, what is the work input required for this process?

Given
  • Air mass = 0.2 kg
  • Initial pressure = 100 kPa
  • Initial temperature = 300 K
  • Final pressure = 600 kPa
  • k = 1.4
  • Cv = 0.718 kJ/(kg·K)
FindWork input (kJ)

Solution

T2 = T1(p2/p1)(k − 1)/k = 300 × 60.2857 = 500.6 K

Win = m·cv(T2 − T1) = 0.2 × 0.718 × 200.6 = 28.8 kJ ≈ 29 kJ

FE Reference Handbook, Thermodynamics: ideal gas isentropic process; closed-system first law.

m·R·ΔT is the boundary work of a constant-pressure process, not of an adiabatic compression.
T2 = 300 × 60.286 = 500.6 K; for a closed system W = m·cv(T2 − T1) = 0.2 × 0.718 × 200.6 ≈ 29 kJ.
m·R·T·ln(6) is the work of an isothermal compression; an isentropic process follows a different path.
m·cp·ΔT is the work of a steady-flow compressor; a piston-cylinder (closed) system uses cv.
Using exponent k − 1 on the pressure ratio overstates T2; with pressures the exponent is (k − 1)/k.
Question 10 of 18 · Thermodynamics · 10–15 items

An adiabatic compressor takes in superheated vapor at 100 kPa and compresses it to 500 kPa with an isentropic efficiency of 80%. Using the property table for the real fluid below, what is the actual work required per unit mass of fluid?

StatePressure (kPa)Temperature (°C)Enthalpy (kJ/kg)Entropy (kJ/(kg·K))
Inlet10015021007.20
Exit A50028028607.20
Exit B50035030507.55
Exit C50042032407.90
Given
  • Inlet: 100 kPa, 150 °C, h = 2100 kJ/kg, s = 7.20 kJ/(kg·K)
  • Exit A: 500 kPa, h = 2860 kJ/kg, s = 7.20 kJ/(kg·K)
  • Exit B: 500 kPa, h = 3050 kJ/kg, s = 7.55 kJ/(kg·K)
  • Exit C: 500 kPa, h = 3240 kJ/kg, s = 7.90 kJ/(kg·K)
  • Isentropic efficiency η = 80%
FindActual work (kJ/kg)

Solution

ws = h2s − h1 = 2860 − 2100 = 760 kJ/kg (state A, s2 = s1)

wa = ws/ηc = 760/0.80 = 950 kJ/kg

FE Reference Handbook, Thermodynamics: isentropic efficiency of compressors.

Multiplying by the efficiency is the turbine form; a compressor needs more work than the isentropic ideal.
760 kJ/kg is the isentropic work; the 80% efficiency raises the actual work.
The isentropic exit is state A (same s): ws = 2860 − 2100 = 760 kJ/kg, and wactual = ws/η = 760/0.80 = 950 kJ/kg.
This reads state C as the exit; the actual exit enthalpy is 2100 + 950 = 3050 kJ/kg, which is state B.
Question 11 of 18 · Thermodynamics · 10–15 items
StreamFluid stateSpecific enthalpyMass flow rate
1Superheated steamh1ṁ1
2Cooling waterh2ṁ2
3Saturated steamh3ṁ3

A direct-contact desuperheater is used in an industrial facility to reduce the temperature of a steam supply. Superheated steam is mixed with cooling water to produce saturated steam at the exit. The device operates at steady state and is well-insulated. Based on the variable definitions in the provided table, which system of equations correctly represents the complete mass and energy conservation balances for this device?

Solution

Mass: ṁ1 + ṁ2 = ṁ3

Energy (Q̇ = Ẇ = 0, ΔKE ≈ ΔPE ≈ 0): ṁ1h1 + ṁ2h2 = ṁ3h3

The device is well insulated, so there is no heat-loss term.
This treats the cooling water as an outlet; both streams 1 and 2 enter.
The cooling water's energy flow enters the device, so it adds rather than subtracts.
Specific enthalpies do not add; each must be weighted by its mass flow.
An insulated mixing device with no work conserves mass and enthalpy flow: what comes in leaves in the single exit stream.
Question 12 of 18 · Thermodynamics · 10–15 items

For one mole of an ideal gas undergoing a reversible isothermal expansion at 350 K, the pressure decreases from 5 atm to 1 atm. Calculate the change in entropy of the system.

Given
  • Amount n = 1 mol
  • Temperature T = 350 K
  • Initial pressure p1 = 5 atm
  • Final pressure p2 = 1 atm
FindEntropy change ΔS (J/K)

Solution

ΔS = nR ln(p1/p2) = (1 mol)(8.314 J/(mol·K)) ln(5/1) = 13.4 J/K

FE Reference Handbook, Thermodynamics: ideal gas entropy change.

Using ln(p2/p1) flips the sign; entropy rises when a gas expands.
This uses log10 5 instead of the natural logarithm.
This is R alone; the pressure ratio enters through ln(p1/p2).
For an isothermal ideal gas, ΔS = nR ln(p1/p2) = 1 × 8.314 × ln 5 = 13.4 J/K.
Question 13 of 18 · Thermodynamics · 10–15 items

An ideal diatomic gas (k = 1.4) undergoes a reversible adiabatic expansion in which its volume increases by a factor of 4. What happens to its absolute temperature?

Given
  • Specific heat ratio k = 1.4
  • Volume ratio V2/V1 = 4
FindTemperature ratio T2/T1

Solution

T2/T1 = (V1/V2)k − 1 = (1/4)0.4 = 0.574

FE Reference Handbook, Thermodynamics: ideal gas isentropic process.

T2/T1 = (V1/V2)k − 1 = (1/4)0.4 = 0.574.
43% is the drop, 1 − 0.574, not the remaining fraction.
Temperature stays constant only in an isothermal expansion; an adiabatic expansion does work at the expense of internal energy.
(1/4)0.286 uses the pressure-ratio exponent (k − 1)/k with a volume ratio.
Question 14 of 18 · Thermodynamics · 10–15 items

On a T-s diagram for a pure substance, what does the area under the curve of a reversible process represent?

Solution

qrev = ∫T ds (area under the path on the T-s diagram)

Work is the area under the path on a p-v diagram, not a T-s diagram.
For a reversible process δq = T ds, so the area under the curve on T-s axes is the heat transferred per unit mass.
Internal energy is a property change set by the end states; the area under the path depends on the path.
Enthalpy change equals the area only in a reversible constant-pressure process; in general it does not.
Question 15 of 18 · Thermodynamics · 10–15 items

For a pure substance, at what condition do the liquid and vapor phases have the same density?

Solution

Critical point: vf = vg, hfg = 0 (water: 374 °C, 22.06 MPa).

At the critical point the saturated liquid and vapor lines meet, and the two phases become indistinguishable with equal density.
At the triple point three phases coexist, each with its own distinct density.
At the freezing point solid and liquid coexist; liquid and vapor densities are far apart.
At ordinary boiling, vapor density is far below liquid density, about 1/1600 for water at 1 atm.
Question 16 of 18 · Thermodynamics · 10–15 items

A Carnot engine operates between reservoirs at 650 K (hot) and 300 K (cold). If the engine absorbs 500 kJ of heat from the hot reservoir, what is the amount of heat rejected to the cold reservoir?

Given
  • Hot reservoir TH = 650 K
  • Cold reservoir TC = 300 K
  • Heat absorbed QH = 500 kJ
FindHeat rejected QL (kJ)

Solution

QL = QH·TL/TH = 500 × 300/650 = 230.77 kJ

FE Reference Handbook, Thermodynamics: Carnot cycle.

For a Carnot engine QL/QH = TL/TH, so QL = 500 × 300/650 = 230.77 kJ.
This is the net work QH − QL, not the heat rejected.
Rejecting all the heat absorbed would mean zero work output; a Carnot engine converts 54% of it.
Using TH/TL instead of TL/TH (500 × 650/300) makes the heat rejected exceed the heat absorbed.
Question 17 of 18 · Thermodynamics · 10–15 items

For an isentropic steam turbine with a known inlet state, which exit-state property must be found from the steam tables to compute the turbine work?

Solution

wT = h1 − h2s, h2s = h(p2, s2 = s1)

FE Reference Handbook, Thermodynamics: steady-flow devices (turbines).

Pressure alone does not fix the exit state; a second property (s2 = s1) is needed, and the work is the enthalpy difference.
Specific volume enters boundary or flow work for liquids, but turbine work comes from the enthalpy drop.
Turbine work per unit mass is h1 − h2; for an isentropic turbine the exit state is fixed by the exit pressure and s2 = s1.
Temperature alone does not give the work, and in the wet region it does not even fix the state.
Question 18 of 18 · Thermodynamics · 10–15 items

A simple Brayton cycle operates with air flowing at steady state. Air enters the compressor at 300 K and exits at 550 K. Following heat addition, the air enters the turbine at 1300 K and exits at 720 K. Assuming constant specific heats with cp = 1.005 kJ/(kg · K), determine the net specific work output of the cycle.

Given
  • Compressor inlet T1 = 300 K
  • Compressor exit T2 = 550 K
  • Turbine inlet T3 = 1300 K
  • Turbine exit T4 = 720 K
  • cp = 1.005 kJ/(kg·K)
FindNet specific work (kJ/kg)

Solution

wT = cp(T3 − T4) = 1.005 × 580 = 582.90 kJ/kg, wC = cp(T2 − T1) = 1.005 × 250 = 251.25 kJ/kg

wnet = wT − wC = 331.65 kJ/kg

FE Reference Handbook, Thermodynamics: Brayton cycle.

This is the compressor work alone, cp(550 − 300); the cycle's net work is turbine minus compressor.
wnet = cp[(T3 − T4) − (T2 − T1)] = 1.005 × (580 − 250) = 331.65 kJ/kg.
This is the turbine work alone; part of it drives the compressor.
cp(1300 − 550) is the heat added in the combustor, not the net work.
Adding the compressor work to the turbine work gets its sign wrong; the compressor consumes work.

Answer every question to see your score

Common traps

Checked against the Thermodynamics chapter of the FE Reference Handbook and Çengel and Boles, Thermodynamics: An Engineering Approach:

  • Absolute temperature. Ideal-gas relations, entropy changes and every Carnot limit use kelvin or rankine. A ratio of Celsius temperatures is meaningless.
  • Closed or open system. A piston-cylinder is a closed system and its energy balance uses internal energy u. A turbine, compressor or nozzle with steady flow uses enthalpy h. Choosing the wrong one drops the flow work.
  • Isentropic efficiency runs both ways. For a turbine, actual work is smaller than isentropic work; for a compressor or pump, actual work is larger. Divide or multiply accordingly.
  • Locate the state before reading a table. Compare the given pressure or specific volume with saturation values first. Interpolating inside the two-phase table for a superheated state is a common, confident mistake.
  • R must match the units. The specific gas constant goes with kg or lbm, the universal constant with moles; pressure in pv = RT is absolute (gauge versus absolute).
  • Sign of work. Texts differ on whether work done by the system is positive. Pick one convention and check the sign of the answer against the physical picture.

Psychrometrics: the basics here, the systems on the PE

The outline includes psychrometrics and HVAC processes, so expect a question or two on reading moist-air properties at sea level and on an ideal vapor-compression cycle. Coil processes, mixing of outdoor and return air and loads are covered in depth on PE HVAC&R loads and psychrometrics, real refrigeration equipment on PE HVAC&R equipment and components.

Other FE Mechanical areas

Thermodynamics, quick answers

Are steam tables provided on the FE exam?

Yes. Steam and refrigerant property tables and charts are part of the on-screen FE Reference Handbook. Practice finding a state with the Handbook's search box, because Ctrl+F does not work on exam day.

How many thermodynamics questions are on the FE Mechanical exam?

10–15, one of the four largest ranges in the outline alongside dynamics, fluid mechanics and mechanical design.

More thermodynamics problems on your phone

FE Mechanical questions, answers and worked solutions in a study app.

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